i've read several reviews and there isn't much between them. i have a 85mm lens (on a full frame body mind) and it's a very nice length for portraits, either the 85 or 100 on a crop will be quite long though spot on for outdoors.
you might find the reviews for each lens on the digital picture to be of help:
the 85 1.8 does suffer from purple fringing - this isn't something i've seen mentioned about the 100 f2.
also, if you are edging towards the 85mm then take a look at the Sigma 85 1.4 if you want something a bit better than the Canon. I have the Sigma 85 1.4 and it's a truly excellent lens. I can post some sample photos/100% crops if you would like.
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