If you were imaging planets, yes, but the planet would be so small on the sensor that you'd have to crop in a great deal. Plus the video sizes would be massive compared to a web cam, so it's not really anywhere near as practical. If you used a 500mm lens, and teleconverters, you may be able to shoot video of Jupiter or Saturn, but that's about all.
You can only do video with very bright objects.
With deep sky objects such as nebulae and galaxies, no, because each exposure needs to be minutes long.