So you want to adjust a band of exposure across the middle of the image? - Presumably to lighten the buildings?
What I'd do is adjust the exposure to get the buildings where I wanted them and then do highlights and shadows to correct the rest of the image.
Obviously if you increase the overall exposure to lighten the buildings it will start to wash the sky out, so I'd
then use the grad filter to darken the sky.
Don't forget you can use the graduated filter more than once over different areas to get the adjustment you need.
If the foreground is too light you can use the grad again but drag it upwards from the bottom edge, so the filter is only applied to the bottom of the image.
And don't forget you can both darken
and lighten with the grad filter, dependent on the settings.
I'm a fan of the Julieanne Kost tutorial videos so I'd highly recommend you take a look at
this Adobe tutorial about using the graduated and radial filters.
She explains it a lot better than I can.
Another option is to apply a local lightening to the area desired using the Adjustment brush.