Lightroom 3 Export..?

Which way are you trying to export? from the export button in library mode or right clicking in develop mode, if you click choose are you getting a full list there?
 
I'm on a Mac so it may be different if you are on a PC.

When you export you should get a dialogue box come up.Under export locations, when you select the "CHOOSE" button it should give you a list of locations where you can save the images.

When you do this , are you not seeing other locations ?
Are the other drives on the computer or are they external ones
Are you logged on as an administrator or user ?
How are you exporting ? You can use the menu option, Export from Library, or use the short cut cmd/ctrl + Shift + E
 
Can you send a screencap of the dialogue?
There's one of the folder selection dialogue in lr3 that that seems a bit bugged for me, you can type c: in to the text box available and hit enter and it will show all drives again.
 
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