Hi,
Li-on batteries will take approximately 1 year to lose 15-25% of their charge at normal room temperature....faster if they are kept in a warmer environment and far less if kept in the fridge....ie, better to store them out in the garage over winter than in the airing cupboard...dry and low humidity of course.
Be aware that you should never keep them fully charged for long periods without use....much better to store them half discharged and re-charge before use.
They will also last longer (more charge/discharge cycles) if they are recharged before becoming almost fully discharged.
Canon-wise, I remove them when there is one bar left on the LCD (equates to about 15% charge remaining).
Your flash batteries may be Ni-cad or Ni-Mh and slightly different rules apply.
So Chici-whatsit.....don't worry about charging a day or so ahead...they'll be fine when you need 'em.
Bob