Just to throw another opinion in there...
I own the Sigma 50mm 1.4 and the Canon 85mm 1.8 primes, and I love them both. I've also just ordered the Sigma 35mm 1.4. I use a 5D.
Out of the two I currently own, the 50mm has gotten far more use - mainly photos of my kids and friends, but also at the few weddings I've shot. I agree completely with the comments that it's a bit too wide for your usual portrait shot, and a bit too long for indoor shots, but it is very usable. Much more so than the 85mm.
However, if I'm shooting your typical portrait shots, the 85mm wins every time. Unless you're going for a more environmental portrait, in which case the 50mm is pretty good, but it's kind of inbetween being wide enough for an environmental portrait and long enough for a single person portrait.
So, I will probably sell my 50mm as soon as the 35mm arrives, and keep my 85mm.
However, if I didn't have the option of the 35mm there is no way on earth I would sell my 50mm. The 85mm delivers when you need it, but if you are looking at having just one prime, I'd say the 50mm would be the best choice. You don't realise how tight 85mm is until you are suddenly in a situation where you need to get more than one person in a shot, or get a full length portrait. When that happens (and it will happen, a lot) I reckon you'd wish you went for the 50mm.
If on the other hand you plan to add a wider prime to your collection in future - get the 85mm, either Sigma or Canon. From my experience of the Canon it is brilliant. I certainly have no urge to buy the Sigma, or indeed the Canon 85mm f/1.2. It really is very good indeed.
It's hard to shoe-horn this in without sounding like I'm trying to sell something, but...my Sigma 50mm might be up for grabs soon. It's been in to Sigma for calibration and is now pretty much perfect. I'm just waiting to take delivery of my Sigma 35mm before I decide whether I can live without it!
Edit: If I do sell it I will post it in the classifieds section, as per the rules!