Free software to play with?

Well you're free to play with the full version of Photoshop CS5 for 30 days.
 
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I'd also look at Elements, Lightroom is pretty my h the best application for photographers, the main thing it lacks are layers.

The main plug in for B&W is SilverFX Pro, maybe worth a look.

Have you looked at different ways of using the develop module for black & white in Lightroom?
 
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