That's why I said a 'master flash gun' outputs normal light. I was not referring to the ST-E2, though that is basically just a small flashgun with a very dark red filter over the front. Near-IR if you like, but it can't be true IR as there's next to none of that coming from the flash tube behind it.
And yes, and ST-E2 will fire a remote Canon gun in manual, but it still uses E-TTL communication to do it, ie there's still a pre-flash, and that will screw up anything firing off a regular optical slave.
Canon system is great when used with Canon equipment, but it's quirky (maybe it's that patents thing again) and if you tread off the recommended path it may not work as expected.