Hi fish, and welcome to TP.
(which works since the blue colour is
caused by the scattering of sunlight).
QUOTE]
I believe its the opposite to what you have suggested here. Light is scattered by air particles, which causes a reduction in the blueness of the sky. The polariser cuts out the scattered light allowing through only polarised light.
Skies are bluer after the passage of a cold front which contains fewer air particles, therefore less light is scattered. Also the sky is bluer vertically above where light has to pass through less atmosphere, and is therefore less scattered.
But apart from that I agree with what you say.
The best thing to do with a polariser is to try one out. You can see exactly what you will be getting through the viewfinder of your SLR. As well as the obvious effects mentioned above, they can have all sorts of subtle effects which you can use in your pics once you recognise them.