Trev
Using the pen tool does take a bit of practice. However this is the basic idea. select the pen tool ( Obvious) . now on part of the image you want to select, click to make a start point. now in small increments click on other parts. You'll see it start to draw line. Curves can very difficult, There are some techniques for this, but a lot of straight lines can give you a curved effect following the curve. ( I'm keeping it simple at the moment). Now when you get back to where you started, you need to turn this path into a selection. In CS4 you simply right click and select Make Selection. You also get an option to feather the edge of the selection. This depends on if you want a hard edge or a soft. If soft try between 5-8 pixels.
Now you can copy, invert, cut or whatever you want. Takes a bit of time to prefect but it is useful.
One advantage especially with complex shapes , i.e. the spokes of a wheel, you can make multiple selections and add them together to make one selection.
I've tried to find decent tutorials on the pen tool but not found anything that's anything more than basic. If you find any let me know
John C