YN 560iii is a manual-only gun. And it's none the worse for that (thinking of getting a few of them myself). Also consider the new YN 560-TX remote controller for it

But as a manual gun, it doesn't have any of the distance information that auto-TTL guns have - you just set the power output according to the situation, and that's that.
Outdoors, the starting point is always the ambient light level, because that's fixed, then adjust flash brightness to suit. There are three ways: move the flash forward/back and at close-ish range this will have a big impact on effective brightness (inverse square law). Or you can adjust the power output of course, and a third way is to zoom the flash head which adjusts the coverage of the flash beam and therefore the effective brightness. Or any combination of all three, though the ideal method is to position the flash where you want it for best effect, adjust zoom head as necessary, then adjust power to suit, but sometimes situations are not ideal so you have to mix and match.
There are no rules to exposure, and quite likely 'correct' flash exposure (which is what an auto-TTL gun will attempt to achieve) won't look best. Fill-in flash where you just want to lift the shadows doesn't need that much power and less flash output tends to look best. Balancing flash and daylight exactly needs more poke and the brighter the flash becomes the more obvious and unnatural it can appear. Or you might want to over-power the daylight to turn the background dark, but this often needs tons of power, more than most speedlites have, and since the flash is then dominant, the quality of that light becomes very important - think small softbox (quite an advanced technique to do well).
Overriding all this is shutter speed that must stay at or below the camera's x-sync maximum - 1/200sec on a D3100, and on a sunny day it can often rise above that. 'High-speed sync' was invented to help get around this, but that's not available on the YN 560iii (or your camera, I think) so you have to use aperture and/or ISO to push the shutter speed down if necessary.
Rogue FB is a great accessory, but not so much outdoors. It's very versatile, but primarily intended to direct the flash partly towards a bounce surface like ceiling or wall (to create nice, soft light) and partly direct towards the subject. Outdoors the main benefit is lost and it'll waste a great deal of light in the process.