If you have a musty smell from your air conditioning, then these do work OK for a while. One I tried lasted a few weeks, but another just a few days.
The thing I found worked the best was spray cans of dettol all in one for about £3 in the supermarket. The same product is called Lysol elsewhere in the world. It eliminates the mould spores that can build up on the fins of the AC condenser and in nooks and crannies of your AC plumbing.
Find the air intake for your AC, and with the engine running and the AC on and fans at max, spray about 1/3 of the contents into the air intake. Every minute switch off the AC but keep the fans running (spray some more in), switch on the AC, spray some more in, switch from air coming in from the outside to recirculation mode, spray some more in, and so forth. Repeat until the can is empty. This ensures that every tube and path for air coming into your car will have had a good coating of the stuff.