So, as noted above, I went to the folder in my Master Files, the exact folder that was imported into C1Pro. I opened the (Jpeg) file above in Affinity Photo, which says it is in sRGB IEC61966-2.1. Select Colour Picker, and I cannot find any point which is not grey (R=G=B). The same file has been imported into C1Pro, which says the colour space is sRBG IEC-61966-2.1. The top left (adjusted) histogram shows different curves for R, G and B, and it's easy to find spots with different values, as mentioned above.
At this point I'm pretty sure that Vuescan is ruled out as the cause of my problem, particularly as the same behaviour happens for a file scanned in 2013 using SilverFast SE 6. I don't know what the heck is going on, but it seems like C1Pro in this version is at fault. Possibly something's going wrong on import, certainly the Black and White control is not doing its job. I have a recently developed film ready for scanning, when that's imported I need to remember to set C1Pro to make no adjustments on import. So far I have asked it to remove the adjustments made, which ought to have the same effect, I but need to be sure.
Of course, no-one at Capture One would be interested, as it's an old version.
These effects are relatively minor, and I've not really noticed the effect over the past year or two, o maybe it's no big deal. But I have been struggling trying to get neutral black and white prints. I used to put that down to my cheap 12-year-old printer, but I recently bought an ET-8550, and I still struggle to get a neutral print, despite following all the best advice I can get. It will be interesting to try print an un-adjusted image from C1Pro and compare it with a print from Affinity Photo!