I found this out the hard way running a workshop and none of the Canon bodies that the attendees had could do rear curtain with the dumb studio triggers - the cameras simply had no functionality for rear curtain sync - unless we attached a Speedlite. I suspect it works by passing the shutter speed to compatible Speedlites or triggers which can then work out when to actually fire, but the actual centre pin impulse always comes at the start.
We came up with 2 solutions: as we were using fairly long exposures of 1-6 seconds, and sometimes on bulb mode, I fired the flashes manually using the test button on the trigger and the photographer then closed the shutter when they saw the flash. A better solution was to just mount a Canon Speedlite on the camera, set rear curtain sync on that and aim it, at low power, at the slave cell of a studio light. I can't remember now, but this option may not work for bulb shooting (as the camera has no idea at the start of the exposure, how long it will be).