I feel your pain!
Basically, get the rear wheel aligned as well as you can - look along both sides of the tyre and get the same amount of headstock visible. Make sure the chain doesn't get tight while you're doing that. Have a look for any index marks by the adjusters - they might be accurate!
Now, find the tight spot of the chain by slowly turning the wheel while your finger is gently pressing against the outside of the chain, half way between the sprockets.
Loosen the lock nuts on the adjusters and finger tighten the adjuster bolts.
Going about 1/4 turn each time on each side, adjust the chain so there's a little slack in the chain at the tight point.
Once you're happy with the chain tension and alignment, tighten the axle nuts, check the tension again then (if still happy) tighten the lock nuts on the adjusters while holding the adjusters themselves to stop them turning.
Or, take it to a decent bike shop and pay them a few quid to set the bike up properly!