I have the 150-600C and the 100-400, albeit the MK1.
In my experience, the Canon is ultra sharp, I can only imagine the Mk2 is even better. I may have a good copy of the Mk1 and I can't imagine anything being sharper, so I've never upgraded.
The Sigma I have found to also be very sharp, almost, if not as sharp as the Canon. The extra reach is also very nice and I use the Sigma more often than not. The Canon though is smaller and easier to carry around as at 100mm, it's quite small, for a telephoto.
I'd use the Sigma for hide work and the Canon as a walkaround.
If I had to choose, I'd probably go for the Canon, (especially the Mk2 now), you really can't beat native. Native will also make the best use of the sensor.